Two-phase material with surprising properties

Microscopic polymer structures - Microstructure and macroscopic electro-mechanical properties are closely coupled in so-called ferroelectric polymers. An explanation for the high temperature dependence of this coupling has now been found at TU Wien. In certain materials, electrical and mechanical effects are closely linked: for example, the material may change its shape when an electrical field is applied or, conversely, an electrical field may be created when the material is deformed. Such electromechanically active materials are very important for many technical applications. Usually, such materials are special, inorganic crystals, which are hard and brittle. For this reason, so-called ferroelectric polymers are now being used. They are characterised by the fact that their polymer chains exist simultaneously in two different microstructures: some areas are strongly ordered (crystalline), while disordered (amorphous) areas form in between.